[1]徐建锋,杨文斌*,吴秋宁,等. 可逆热致变色结晶紫内酯微胶囊的性能表征[J].西北林学院学报,2014,29(04):188-192.[doi:doi:10.3969/j.issn.1001-7461.2014.04.33]
　XU Jian-feng,YANG Wen-bin*,WU Qiu-ning,et al. Performance Characteristics of Reversible Thermochromism Crystal Violet Lactone Microcapsule[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2014,29(04):188-192.[doi:doi:10.3969/j.issn.1001-7461.2014.04.33]
点击复制

 可逆热致变色结晶紫内酯微胶囊的性能表征()
分享到：

《西北林学院学报》[ISSN:1001-7461/CN:61-1202/S]

卷:
第29卷
期数:
2014年04期
页码:
188-192
栏目:
出版日期:
2014-07-30

文章信息/Info

Title:
 Performance Characteristics of Reversible Thermochromism Crystal Violet Lactone Microcapsule
文章编号:
1001-7461(2014)04-0188-05
作者:
 徐建锋1; 杨文斌1*; 吴秋宁2; 杨越飞3
 （1.福建农林大学 材料工程学院，福建 福州 350002；2.福建农林大学 国有资产管理处，福建 福州 350002;3.国家人造板及林化工产品质量监督检验中心，福建 三明 365000）
Author(s):
 XU Jian-feng1;  YANG Wen-bin1*;  WU Qiu-ning2;  YANG Yue-fei3
 (1. Material Engineering College, Fujian Agriculture and Forestry University, Fuzhou, Fujian 350002, China; 2. State-owned Assets Administration, Fujian Agriculture and Forestry University, Fuzhou, Fujian 350002, China;3.National Wood and Forest Product of Chemical Quality Supervision and Inspection, Sanming, Fujian 365000, China)
关键词:
 ; 热致变色;  结晶紫内酯微胶囊;  性能表征
Keywords:
 ; thermochromism;  crystal violet lactone microcapsule;  characterization
分类号:
TQ413.23
DOI:
doi:10.3969/j.issn.1001-7461.2014.04.33
文献标志码:
A
摘要:
 分别对自制可逆热致变色结晶紫内酯微胶囊和市售蓝色微胶囊进行显微结构观察、粒径分析，测定未处理的微胶囊的变色温度与变色时间，对其进行加热、浸泡有机溶剂、浸泡化学试剂、升降温处理，再测定其变色温度与变色时间。结果表明，和市售蓝色微胶囊相比，自制结晶紫内酯微胶囊粒径较小，变色较灵敏，具有较好的分散性，但变色温度范围较小。自制结晶紫内酯微胶囊具有较好的耐有机溶剂性能和化学稳定性能，两者均有优良的耐热老化性能和耐疲劳性能。
Abstract:
 Microstructure observation and grain size analysis of self-made and commercially available blue capsul was carried out respectivelg. Temperatures and time at which the color of capsule began to change were measured. The results demonstrated that compared with the commercial blue microcapsule, the self-made capsule had smaller grain size, color-changing was more sensitive and had better dispensability, but the color-changing temperature range was limited. And the self-made microcapsule had better resistance to organic solvent and chemical stability, two microcapsules had excellent resistance to heat and aging, as well as to fatigue.

参考文献/References:

 [1]李文戈, 朱昌中, 王文芬, 等. 可逆热致变色材料 [J]. 功能材料, 1997,28(4):337-341.
[2]MUTHYALA R. 隐色体染料化学与应用 [M]. 董川, 双少敏,译. 北京：化学工业出版社, 2010.
[3]张澎声. 可逆热致变色材料 [J]. 染料工业, 2002,39(6):16-18.
[4]王旭东, 徐伟箭. 可逆热致变色材料的应用新进展 [J]. 化工进展, 2000,19(3):42-45.
[5]JALIL R, NIXON J R. Microencapsulation using poly (DL-lactic).IV: Effect of storage on the microcapsule characteristics [J]. Microencapsule, 1990,7(3):375-383.
[6]崔晓亮, 张宝砚, 孟凡宝, 等. 一种可逆热致变色材料的制备及微胶囊化研究 [J]. 合成树脂及塑料, 2002,19(3):24-27.
[7]陈建山, 周钢, 吴宇雄, 等. 微胶囊制备技术及其应用 [J]. 精细化工中间体, 2003, 33(6):17-19.
[8]吴秋宁, 宋剑斌, 余方兵, 等. 可逆热致变色竹塑复合材料的温度与光响应及热学性能 [J]. 农业工程学报, 2013,29(14):277-283.
WU Q N, SONG J B, YU F B, et al. Response to temperature and light and thermal property of reversibly thermochromic bamboo/plastic composite [J]. Transactions of the Chinese Society of Agricultural Engineering, 2013,29(14):277-283.(in Chinese)
[9]吴秋宁, 杨文斌, 余方兵, 等. 可逆热致变色竹塑复合材料的性能 [J]. 高分子材料科学与工程, 2013,29(4):41-45.
WU Q N, YANG W B, YU F B, et al. Properties of reversibly thermochromic bamboo/plastic composite [J]. Polymer Materials Science and Engineering, 2013,29(4):41-45.(in Chinese)
[10]KARLESSI T, SANTAMOURIS M, APOSTOLAKIS K, et al. Development and testing of thermochromic coatings for buildings and urban structures [J]. Solar Energy, 2009,39 (2):90-94.
[11]马一平. 常温可逆热致变色水泥基材料的研制 [J]. 建筑材料学报, 2006,9(6):700-704.
[12]CHARIS R, THEOCHARIS, WILLIAM J. Crystal structure of 3,3-(p-N,N-dimethylaminophenyl)-6-N,N-dimethylaminophthalide,(crystal-violet lactone) [J]. Journal of Crystallographic and Spectroscopic Research, 1984,14(2):121-128.
[13]阳年发, 郑兴良, 杨利文. 结晶紫内酯的合成 [J]. 精细化工, 1999,16(2):28-30.
[14]丁玲, 沈宗璇. 结晶紫内酯的合成探讨 [J]. 苏州大学学报：自然科学, 2002,18(4):85-91.
DING L, SHEN Z X. Synthesis of crystal violet lactone [J]. Journal of Suzhou University ：Natural Science Edition, 2002,18(4):85-91.(in Chinese)
[15]陈丽娜, 白国信, 叶明新. 油溶性结晶紫内酯的合成与性能 [J]. 复旦学报:自然科学版, 2006,45 (3):375-379.
CHEN L N, BAI G X, YE M X. The synthesis and properties of oil-soluble butyl crystal violet lactone [J]. Journal of Fudan University ：Natural Science Edition, 2006,45(3):375-379.(in Chinese)
[16]刘军, 赵曙辉, 李文刚, 等.结晶紫内酯可逆热致变色复配物的DSC研究 [J]. 印染助剂, 2003,20(6): 39-41.
[17]张明昕, 吴秋宁, 杨文斌. 结晶紫内酯变色过程的计算模拟与实验探索 [J]. 分子科学学报, 2012,28 (6):448-452.
ZHANG M X, WU Q N, YANG W B. Exploring chromic transition of crystal violet lactone via theoretical and experimental methods[J]. Journal of Molecular Science, 2012,28(6):448-452.(in Chinese)
[18]宋健, 李光天, 程侣柏. 结晶紫内酯变色机理的研究 [J]. 大连理工大学学报, 1999,39(3):410-414.
SONG J, LI G T, CHENG L B. Study on chromic mechanism of crystal violet lactone [J]. Journal of Dalian University of Technology, 1999,39(3):410-414.(in Chinese)
[19]VIST M R, DAVIS J H. Phase equilibria of cholesterol/dipalmitoylphosphatidylcholine mixtures: 2H nuclear magnetic resonance and differential scanning calorimetry[J]. Biochemistry, 1990,29(2):451-464.

相似文献/References:

[1]李亚藏,梁彦兰,王庆成. 铅对山梨和山荆子光合作用和叶绿素荧光特性的影响[J].西北林学院学报,2012,27(05):21.
　LI Ya-cang,LIANG Yan-lan,WANG Qing-cheng. Influence of Pb on Photosynthesis and Chlorophyll Fluorescence Characteristics in Pyrus ussuriensis and Malus baccata [J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2012,27(04):21.
[2]张小咏,李佳,杨艳昭,等. 基于SWAT模型的长江源区径流模拟[J].西北林学院学报,2012,27(05):38.
　ZHANG Xiao-yong,LI Jia,YANG Yan-zhao,et al. Runoff Simulation of the Catchment of the Headwaters of the Yangtze River Based on SWAT Model[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2012,27(04):38.
[3]杨红旗,陈广辉,王金林. PVAc改性酚醛树脂制备铝木复合材料研究[J].西北林学院学报,2013,28(01):170.[doi:10.3969/j.issn.1001-7461.2013.01.34]
　YANG Hong-qi,CHEN Guang-hui,WANG Jin-lin. PF Adhesive Modified by PVAc for Manufacturing Technology of Decorative Fiberboard with Aluminum Foils[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(04):170.[doi:10.3969/j.issn.1001-7461.2013.01.34]
[4]江涛,李秀荣,谢延军,等. 微波预处理对巨尾桉木材渗透性的影响[J].西北林学院学报,2013,28(01):174.[doi:10.3969/j.issn.1001-7461.2013.01.35]
　JIANG Tao,LI Xiu-rong,XIE Yan-jun,et al. Effects of Microwave Pretreatment on the Permeability of Eucalyptus grandis×Eucalyptus urophylla[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(04):174.[doi:10.3969/j.issn.1001-7461.2013.01.35]
[5]牛晓霆,王逢瑚,曹新民. 明清家具匠师原木下料的工艺原则及措施[J].西北林学院学报,2013,28(01):178.[doi:10.3969/j.issn.1001-7461.2013.01.36]
　NIU Xiao-ting,WANG Feng-hu,CAO Xin-min. Techniques and Principles of Log Cuttings of Furniture Makers in Ming and Qing Dynasties[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(04):178.[doi:10.3969/j.issn.1001-7461.2013.01.36]
[6]吕金阳,覃卓凯,舒辉,等. 银杉木材构造美学价值[J].西北林学院学报,2013,28(01):183.[doi:10.3969/j.issn.1001-7461.2013.01.37]
　LV Jin-yang,QIN Zhuo-kai,SHU Hui,et al. Esthetical Values in Wood Structure of Cathaya argyrophylla[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(04):183.[doi:10.3969/j.issn.1001-7461.2013.01.37]
[7]杨艳红,张海敏,孙景荣. 基于传统文化视角的现代家具设计探析[J].西北林学院学报,2013,28(01):188.[doi:10.3969/j.issn.1001-7461.2013.01.38]
　YANG Yan-hong,ZHANG Hai-min,SUN Jing-rong. Study of Modern Furniture Design Based on Traditional Culture[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(04):188.[doi:10.3969/j.issn.1001-7461.2013.01.38]
[8]黄圣游,叶喜. 新中式家具“中式”传统的界定[J].西北林学院学报,2013,28(01):192.[doi:10.3969/j.issn.1001-7461.2013.01.39]
　HUANG Sheng-You,YE Xi. Definition of Traditional Element in New Chinese Style Furniture[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(04):192.[doi:10.3969/j.issn.1001-7461.2013.01.39]
[9]韩维生,赵明磊,王宏斌. 基于阈限理论的设计尺度体系[J].西北林学院学报,2013,28(01):197.[doi:10.3969/j.issn.1001-7461.2013.01.40]
　HAN Wei-sheng,ZHAO Ming-lei,WANG Hong-bin. Design Scale System Based on Threshold Theory[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(04):197.[doi:10.3969/j.issn.1001-7461.2013.01.40]
[10]宋杰,侯建军,申黎明. 按摩椅按摩头包覆层对按摩舒适性的影响[J].西北林学院学报,2013,28(01):202.[doi:10.3969/j.issn.1001-7461.2013.01.41]
　SONG Jie,HOU Jian-jun,SHEN Li-ming. Influence of Massager Coat Layer of Massage Chairs on the Degree of Comfort[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(04):202.[doi:10.3969/j.issn.1001-7461.2013.01.41]

备注/Memo

备注/Memo:
 收稿日期：2013-10-10修回日期：2014-02-16
基金项目：国家自然科学基金项目(31170535, 30771683)。
作者简介：徐建锋，男，硕士研究生，研究方向：木塑复合材料。E-mail:xujianfengv@163.com
*通信作者：杨文斌，男，教授，博士生导师，研究方向：木塑复合材料。E-mail:fafuywb@163.com
更新日期/Last Update: