[1]王辉,吴志刚,席雪冬,等. 新型三聚氰胺-尿素-甲醛树脂制备与研究（Ⅰ）——大豆蛋白水解液改性MUF[J].西北林学院学报,2016,31(1):260-264.[doi:10.3969/j.issn.1001-7461.2016.01.45]
　WANG Hui,WU Zhi-gang,XI Xue-dong,et al. Synthesis and Study of a New Melamine-urea-formaldehyde Resin(Ⅰ)——MUF Resin Modified by Degradated Soy-protein[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2016,31(1):260-264.[doi:10.3969/j.issn.1001-7461.2016.01.45]
点击复制

 新型三聚氰胺-尿素-甲醛树脂制备与研究（Ⅰ）——大豆蛋白水解液改性MUF()
分享到：

《西北林学院学报》[ISSN:1001-7461/CN:61-1202/S]

卷:
第31卷
期数:
2016年第1期
页码:
260-264
栏目:
出版日期:
2016-01-31

文章信息/Info

Title:
 Synthesis and Study of a New Melamine-urea-formaldehyde Resin(Ⅰ)——MUF Resin Modified by Degradated Soy-protein
文章编号:
1001-7461(2016)01-0260-05
作者:
 王辉; 吴志刚; 席雪冬; 曹明; 郭晓申; 雷洪; 杜官本
 （西南林业大学 云南省木材胶黏剂及胶合制品重点实验室，云南 昆明 650224）
Author(s):
 WANG Hui; WU Zhi-gang; XI Xue-dong; CAO Ming; GUO Xiao-shen; LEI Hong; DU Guan-ben
(Wood Adhesives and Glued Products Key Laboratory of Yunnan Province,Southwest Forestry University,Kunming,Yunnan 650224,China)
关键词:
 ; 三聚氰胺-尿素-甲醛树脂; 大豆蛋白; 结构性能; 游离甲醛
Keywords:
 ; MUF;  soy protein;  structure characteristic;  free formaldehyde
分类号:
Q946.86
DOI:
10.3969/j.issn.1001-7461.2016.01.45
文献标志码:
A
摘要:
 以三聚氰胺、大豆蛋白（SPI）降解液、尿素和甲醛为原料，合成了一种改性的三聚氰胺-尿素-甲醛树脂（MUF）。分析了改性后MUF的性能，并借助核磁共振(13C-NMR)、红外光谱（FT-IR）和动态热机械性能（DMA）分析改性后MUF的结构变化和热机械性能。结果表明：当加入10%SPI降解液时，合成的MUF机械性能最优，刨花板内结合强度和静曲强度分别提高30%和46%，游离甲醛含量降低21%。13C-NMR分析表明，加入SPI降解液，可以提高MUF树脂中的亚甲基桥键、亚甲基醚键和三聚氰胺与尿素共缩聚反应产生的亚甲基醚键含量，最终体系具有较高的缩聚度、交联度和较低的游离甲醛。FT-IR分析表明，改性后的MUF酰胺特征峰吸收谱带由明显双肩峰变成单肩峰，表明蛋白质降解液与MUF树脂发生了交联反应。DMA测试结果表明，以大豆蛋白降解液改性MUF，可以显著改善最终胶合产品的热机械性能。
Abstract:
 A new melamine-urea-formaldehyde(MUF) resin based on melamine,degraded soy-protein,urea and formaldehyde were prepared.The structure characteristics and thermal mechanical properties of this new MUF resin were studied by 13C-NMR,FT-IR and DMA.When addition amount of degraded soy protein was 10%,bonding strength and MOR of particleboard respectively increased by 30% and 46%，content of free formaldehyde decreased by 21%.13C-NMR results showed that,the contents of methylene bridges,methylene ether bond and ether bond formed by copolycondensation reaction between melamine and urea increased.Final resin system had high polycondensation and crosslinking degree,low free formaldehyde emission.The FT-IR results indicated that degraded soy protein reacted with MUF.The DMA results showed that this new MUF resin could improve the thermal mechanical performance of the final products.

相似文献/References:

[1]李亚藏,梁彦兰,王庆成. 铅对山梨和山荆子光合作用和叶绿素荧光特性的影响[J].西北林学院学报,2012,27(05):21.
　LI Ya-cang,LIANG Yan-lan,WANG Qing-cheng. Influence of Pb on Photosynthesis and Chlorophyll Fluorescence Characteristics in Pyrus ussuriensis and Malus baccata [J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2012,27(1):21.
[2]张小咏,李佳,杨艳昭,等. 基于SWAT模型的长江源区径流模拟[J].西北林学院学报,2012,27(05):38.
　ZHANG Xiao-yong,LI Jia,YANG Yan-zhao,et al. Runoff Simulation of the Catchment of the Headwaters of the Yangtze River Based on SWAT Model[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2012,27(1):38.
[3]杨红旗,陈广辉,王金林. PVAc改性酚醛树脂制备铝木复合材料研究[J].西北林学院学报,2013,28(01):170.[doi:10.3969/j.issn.1001-7461.2013.01.34]
　YANG Hong-qi,CHEN Guang-hui,WANG Jin-lin. PF Adhesive Modified by PVAc for Manufacturing Technology of Decorative Fiberboard with Aluminum Foils[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(1):170.[doi:10.3969/j.issn.1001-7461.2013.01.34]
[4]江涛,李秀荣,谢延军,等. 微波预处理对巨尾桉木材渗透性的影响[J].西北林学院学报,2013,28(01):174.[doi:10.3969/j.issn.1001-7461.2013.01.35]
　JIANG Tao,LI Xiu-rong,XIE Yan-jun,et al. Effects of Microwave Pretreatment on the Permeability of Eucalyptus grandis×Eucalyptus urophylla[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(1):174.[doi:10.3969/j.issn.1001-7461.2013.01.35]
[5]牛晓霆,王逢瑚,曹新民. 明清家具匠师原木下料的工艺原则及措施[J].西北林学院学报,2013,28(01):178.[doi:10.3969/j.issn.1001-7461.2013.01.36]
　NIU Xiao-ting,WANG Feng-hu,CAO Xin-min. Techniques and Principles of Log Cuttings of Furniture Makers in Ming and Qing Dynasties[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(1):178.[doi:10.3969/j.issn.1001-7461.2013.01.36]
[6]吕金阳,覃卓凯,舒辉,等. 银杉木材构造美学价值[J].西北林学院学报,2013,28(01):183.[doi:10.3969/j.issn.1001-7461.2013.01.37]
　LV Jin-yang,QIN Zhuo-kai,SHU Hui,et al. Esthetical Values in Wood Structure of Cathaya argyrophylla[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(1):183.[doi:10.3969/j.issn.1001-7461.2013.01.37]
[7]杨艳红,张海敏,孙景荣. 基于传统文化视角的现代家具设计探析[J].西北林学院学报,2013,28(01):188.[doi:10.3969/j.issn.1001-7461.2013.01.38]
　YANG Yan-hong,ZHANG Hai-min,SUN Jing-rong. Study of Modern Furniture Design Based on Traditional Culture[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(1):188.[doi:10.3969/j.issn.1001-7461.2013.01.38]
[8]黄圣游,叶喜. 新中式家具“中式”传统的界定[J].西北林学院学报,2013,28(01):192.[doi:10.3969/j.issn.1001-7461.2013.01.39]
　HUANG Sheng-You,YE Xi. Definition of Traditional Element in New Chinese Style Furniture[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(1):192.[doi:10.3969/j.issn.1001-7461.2013.01.39]
[9]韩维生,赵明磊,王宏斌. 基于阈限理论的设计尺度体系[J].西北林学院学报,2013,28(01):197.[doi:10.3969/j.issn.1001-7461.2013.01.40]
　HAN Wei-sheng,ZHAO Ming-lei,WANG Hong-bin. Design Scale System Based on Threshold Theory[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(1):197.[doi:10.3969/j.issn.1001-7461.2013.01.40]
[10]宋杰,侯建军,申黎明. 按摩椅按摩头包覆层对按摩舒适性的影响[J].西北林学院学报,2013,28(01):202.[doi:10.3969/j.issn.1001-7461.2013.01.41]
　SONG Jie,HOU Jian-jun,SHEN Li-ming. Influence of Massager Coat Layer of Massage Chairs on the Degree of Comfort[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(1):202.[doi:10.3969/j.issn.1001-7461.2013.01.41]
[11]王辉,杜官本,梁坚坤. 三聚氰胺-尿素-甲醛共缩聚树脂固化过程分析[J].西北林学院学报,2013,28(04):166.[doi:10.3969/j.issn.1001-7461.2013.04.34]
　WANG Hui,DU Guan-ben,LIANG Jian-kun.Curing Process of MUF Co-polymer Resin[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(1):166.[doi:10.3969/j.issn.1001-7461.2013.04.34]
[12]周晓剑,张俊,王文丽,等. UF树脂和MF树脂共混特性研究[J].西北林学院学报,2020,35(3):202.[doi:10.3969/j.issn.1001-7461.2020.03.32]
　ZHOU Xiao-jian,ZHANG Jun,WANG Wen-li,et al. Blend Characteristics of MF+UF Resin Mixture[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2020,35(1):202.[doi:10.3969/j.issn.1001-7461.2020.03.32]

备注/Memo

备注/Memo:
 收稿日期：2015-03-22修回日期：2015-04-14
基金项目：林业公益性行业科研专项(201304505)；“十二五”国家科技支撑计划项目（2012BAD24B03）；云南省应用基础研究重点项目（2013FA038）；云南省中青年学术带头人后备人才项目（2011HB024）。
作者简介：王辉，女，博士，研究方向:木材胶黏剂与木质复合材料。E-mail：1002469654@qq.com
更新日期/Last Update: