[1]佘雕,耿增超.小麦秸秆木素结构模型的研究进展[J].西北林学院学报,2009,24(01):165-169.
　SHE Diao,GENG Zengchao.Advances in the Researches of Structural Model of Wheat Straw Lignin[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2009,24(01):165-169.
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小麦秸秆木素结构模型的研究进展()
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《西北林学院学报》[ISSN:1001-7461/CN:61-1202/S]

卷:
第24卷
期数:
2009年01期
页码:
165-169
栏目:
出版日期:
2009-01-20

文章信息/Info

Title:
Advances in the Researches of Structural Model of Wheat Straw Lignin
作者:
佘雕;  耿增超
（西北农林科技大学 资源与环境学院，陕西 杨陵 712100）
Author(s):
SHE Diao;  GENG Zengchao
(College of Resources and Environment, Northwest A&F University, Yangling, Shaanxi 712100, China)
关键词:
小麦秸秆; 木素; 结构模型
Keywords:
wheat straw;  lignin;  structural model
分类号:
O636.2
文献标志码:
A
摘要:
主要介绍了小麦秸秆细胞壁中羟基肉桂酸和多糖或/和木素之间的化学键类型、木素和多糖间的连接类型和木素母体间的连接类型等方面的研究进展。并介绍了一种实验性的小麦秸秆木素的化学结构模型。西北林学院学报24卷
Abstract:
The progresses of the bonds between hydroxycinnamic acids and polysaccharides or/and lignin, linkages between lignin and polysaccharides and linkages among the lignin precursors in wheat straw cell walls were reviewed. And a tentative chemical structure of wheat straw lignin is introduced.

参考文献/References:

［1］WALLACE G, FRY S C. Phenolic components of the plant cell wall［J］. International Review of Cytology, 1994, 151 229267.
［2］BJRKMAN. Studies on finely divided wood. 3. Extraction of lignincarbohydrate complexes with neutral solvents［J］. Svensk Papperstidning, 1957, 60 243251.
［3］THEANDER O. New Approaches to Research on Cereal Carbohydrates,(Eds. Hill R D. and Elsevier L M.)(M), Science Publishers B. V., Amsterdam, 1985, 217230.
［4］FORD C W. Comparative structural studies of lignincarbohydrate complex from digitaria decumbens (pangola grass) before and after chlorite delignification［J］. Carbohydr. Research, 1986, 147(1) 101117.
［5］ADLER E. Lignin chemistrypast present and future［J］. Wood Science and Technology, 1977, 11(3) 169218.
［6］SAKALIBARA A. Chemical structure of lignin related mainly to degradation products［M］. In Recent Advances in Lignin Biodegradation Research. Tokyo, UNI publisher, 19831233.
［7］Billae, Monties B. Occurrence of silicon associated with ligninpolysaccharide complexes isolated from Gramineae (wheat straw) cell walls［M］. Food Hydrocolloids, 1991, 5 (1/2) 189195.
［8］Terrón M C, Fidalgo M L, Almendros G, et al. Molecular characterization of alkalilignin1M30C valid alternative preparation to the Bjrkman lignin in the analytical study of wheat straw lignin［J］. Rapid Communications in Mass Spectrometry, 1996, 10 413418.
［9］Jung H J G, Himmelsbach D S. Isolation and characterization of wheat straw lignin［J］. Journal of Agricultural and Food Chemistry, 1989, 37(1) 8187.
［10］Fidalgo M L, TerrnM C, Martinez A T, et al. Comparative study of fractions from alkaline extraction of wheat straw through chemical degradation, analytical pyrolysis, and spectroscopic techniques［J］. Journal of Agricultural and Food Chemistry, 1993, 41(10) 16211626.
［11］BEN GHEDALIA, YOSEF E. Effect of isolation procedure on molecular weight distribution of wheat straw lignins［J］. Journal of Agricultural and Food Chemistry, 1994, 42(3) 649652.
［12］Kondo T, Ohshita T, Kyuma T. Comparison of characteristics of soluble lignins from untreated and ammoniatreated wheat straw［J］. Animal Feed Science and technology, 1992, 39(3/4) 253263.
［13］Kondo T, Watanabe T, Ohsita T, et al. Comparative characterisation of dioxanesoluble lignins released by ball milling and by sheep digestion from forage grasses［J］. Journal of the Science of Food and Agriculture, 1995, 68(3) 383388.
［14］Billa E, Monties B. Molecular variability of lignin fractions isolated from wheat straw［J］. Research on Chemical intermediates, 1995, 21(3/5) 303311.
［15］Iiyma K, Lam T B T. Lignin in wheat straw internodes. Part 1 The reactivities of lignin units during alkaline nitrobenzene oxidation［J］. Journal of the Science of Food and Agriculture, 1990, 51(4) 481491.
［16］SUN R C, Lawther J M, Banks W B. Influence of alkali pretreatment on wheat straw cell wall components［J］. Industrial Crops and Products, 1995, 5(4) 127145.
［17］SUN R C, Lawther J M, Banks W B. The effect of alkaline nitrobenzene oxidation conditions on the yield and components of phenolic monomers in wheat straw lignin and compared to cupric (II) oxidation［J］. Industrial Crops and Products, 1995,5(4) 241254.
［18］SUN R C, Lawther J M, Banks W B. A tentative chemical structure of wheat straw lignin［J］. Industrial Crops and Products, 1997, 6(1) 18.
［19］SUN R C, Lawther J M, Banks W B. Fractional isolation and physicochemical characterization of alkalisoluble lignins from wheat straw［J］. Holzforschung, 1997, 51(3) 244250.
［20］Kolodziejski W, Frye J S, Maciel G E. Carbon13 nuclear magnetic resonance spectrometry with cross polarization and magicangle spinning for analysis of lodgepole pine wood［J］. Analytical Chemistry, 1982, 54 14191424.
［21］SUN R C, Lawther J M, Banks W B. Effects of extraction time and different alkalis on the composition of alkalisoluble wheat straw lignins［J］. Journal of Agricultural and Food Chemistry, 1996, 44(12) 39653970.
［22］SUN R C, Lawther J M, Banks W B. Effects of pretreatment temperature and alkali concentration on the composition of alkalisoluble lignins from wheat straw［J］. Journal of Applied Polymer Science, 1996, 62(9) 14731481.
［23］Lawther J M, SUN R C, Banks W B. Fractional characterization of wheat straw lignin components by alkaline nitrobenzene oxidation and FTIR spectroscopy［J］. Journal of Agricultural and Food Chemistry, 1996, 44(5) 12411247.
［24］Lawther J M, SUN R C, Banks W B. Rapid isolation and structural characterization of alkalisoluble lignins during alkaline treating and atmospheric refining wheat straw［J］. Industrial Crops and products, 1996, 5(2) 97105.
［25］Lawther J M, SUN R C, Banks W B. The fractional characterization of polysaccharides and lignin components in alkaline treated and atmospheric refined wheat straw［J］. Industrial Crops and Products, 1996, 5(2) 8795.
［26］SUN R C, FANG J M, ROWLANDS P. Physicochemical and thermal characterization of alkali lignins from wheat straw［J］. Polymer Journal, 1998, 30(4) 289294.
［27］LAWTHER J M, SUN R C, BANKS W B. Extraction and comparative characterization of ballmilled lignin LM, enzyme lignin LE and alkali lignin LA from wheat straw［J］. Cellulose Chemistry and Technology, 1996, 30 395410.
［28］LAWTHER J M, SUN R C, BANKS W B. Extraction and comparative characterization of ballmilled lignin(LM), enzyme lignin(LE) and alkali lignin (LA) from wheat straw［J］.Cellulose Chemistry and Technology, 1996, 30(5/6) 395410.
［29］LAWTHER J M, SUN R C, BANKS W B. Characterization of dissolved lignins in twostage organosolv delignification of wheat straw［J］. Journal of Wood Chemistry and Technology, 1996, 16 439457.
［30］LAWTHER J M, SUN R C, BANKS W B. Isolation and characterization of organosolv lignin under alkaline condition from wheat straw［J］. International Journal of Polymer Analysis and Characterization, 1997, 3(2) 159175.
［31］SUN R C, LAWTHER J M, BANKS W B. Effect of extraction procedure on the molecular weight of wheat straw lginins［J］. Industrial Crops and Products, 1997, 6(2) 97106.
［32］SUN R C, LAWTHER J M, BANKS W B. Physicochemical characterization of organosolv lignins from wheat straw［J］. Cellulose Chemistry and Technology, 1997, 31(3/4)199212
［33］SUN R C, LAWTHER J M, BANKS W B. The fractional composition of polysaccharides and lignin in alkaline pretreated and steam pressure treated wheat straw［J］. Cellulose Chemistry and Technology, 1996, 30(1/2) 5769.
［34］许凤,孙润仓,詹怀宇.非木材半纤维素研究的新进展［J］.中国造纸学报，2003,18(1)145151.
［35］FRY S C, MILLER J G. Toward a working model of the growing plant cell wall Phenolic crosslinking reactions in the primary cell walls of dicotyledons［J］. ACS Symposium series 399; 1989 3346.
［36］HELM R F, RALPH J. Ligninhydroxycinnamyl model compounds related to forage cell wall structure. 1. Etherlinked structures［J］. Journal of Agricultural and Food Chemistry, 1992, 40(11) 21672175.
［37］SCALBERT A, MONTIES B, GUITTET E, et al. Comparison of wheat straw lignin preparations I. Chemical and spectroscopic characterizations［J］. Holzforschung, 1986, 40(2) 119127.
［38］SCALBERT A, MONTIES B, LALLEMAND J Y, et al. Ether linkage between phenolic acids and lignin fractions from wheat straw. Phytochemistry, 1985, 24 (6) 13591362.
［39］JACQUET G, POLLET B, LAPIERRE C. New etherlinked ferulic acidconiferyl alcohol dimmers identified in grass straws［J］. Journal of Agricultural and Food Chemistry, 1995, 43(10) 27462751.
［40］CRESTINI C, ARGYROPOULOS D S. Structural analysis of wheat straw lignin by quantitative 31P and 2D NMR spectroscopy. The occurrence of ester bonds and αO4 substructures［J］. Journal of Agricultural and Food Chemistry, 1997, 45(4) 12121219.
［41］RALPH J, GRABBER J H, HATFIELD R D. Ligninferulate crosslinks in grasses active incorporation of ferulate polysaccharide esters into ryegrass lignins［J］. Carbohydrate Research, 1995, 275(1) 167178.
［42］ALMENDROS G, MARTINEZ A T, GONZALEZ A E, et al. CPMAS 13C NMR Study of lignin preparations from wheat straw transformed by five lignocellulosedegrading fungi［J］. Journal of Agricultural and Food Chemistry, 1992, 40(7) 12971302.［43］IIYAMA K, LAM T B T, STONE B A. Phenolic acid bridges between polysaccharides and lignin in wheat straw internodes［J］. Phytochemistry, 1990, 29 (3) 733737.［44］LAM T B T, IIYAMA K, STONE B A. Lignin in wheat straw internodes. Part 2 Alkaline nitrobenzene oxidation by wheat straw lignin and its fractions［J］. Journal of the Science of Food and Agriculture, 1990, 51(4) 493506.［45］AHMAD M, KHAN L. Spectroscopic studies of lignins from wheat straw and kai grass［J］. Journal of the Chemical Society of Pakistan,1988, 10(3) 299302.［46］LAM T B T, IIYAMA K, STONE B A. Cinnamic acid bridges between cell wall polymers in wheat and phalaris internodes［J］. Phytochemistry, 1992, 31(4) 11791183.［47］GRABBER J H, HATFIELD R D, RALPH J, et al. Ferulate crosslinking in cell walls isolated from maize cell suspensions［J］. Phytochemistry, 1995, 40(4) 10771082.［48］许 凤，钟新春，孙润仓,等.秸秆中半纤维素的结构及分离新方法综述［J］。林产化学与工业，2005，25（增）179182［49］SHIMADA M, FUKUZUKA T, HIGUCHI T. Ester linkages of pcoumaric acid in bamboo and grass lignins［J］. Tappi, 1971, 54 (1) 7278.［50］NEWBY V K, SABLON R M, SYNGE R L M, et al. Free and bound phenolic acids of lucerne (medicago sativa cv europe)［J］. Phytochemistry, 1980, 19(4) 651657.［51］CHESSON A, GORDON A H, LOMAX J A. Substituent groups linked by alkalilabile bonds to arabinose and xylose residues of legume, grass and cereal straw cell walls and their fate during digestion by rumen microorganisms［J］. Journal of the Science of Food and Agriculture, 1983, 34(12) 13301340.［52］ERIKSSON O, LINDGREN B O. About the linkage between lignin and hemicelluloses in wood［J］. Svensk PapperstidningNordisk Cellulosa, 1977, 80(2) 5963.西北林学院学报 2008, 24(1)170-172

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备注/Memo

备注/Memo:
收稿日期：20080319修回日期：20080522基金项目：国家“973”计划前期研究专项（2006CB708406）作者简介：佘雕，男，讲师，硕士，主要从事农林废弃物资源转化研究。通讯作者：耿增超，教授，硕士生导师，主要从事秸秆化学研究；Eail:gengzengchao@sina.com。
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