[1]刘娇,曹旭东,尚诗媛,等. 竹束热处理对CS/APP自组装重组竹阻燃抑烟性能的影响[J].西北林学院学报,2023,38(3):203-210.[doi:10.3969/j.issn.1001-7461.2023.03.27]
　LIU Jiao,CAO Xu-dong,SHANG Shi-yuan,et al. Effect of Heat Treatment on the Flame Retardancy and Smoke Suppression Performance of CS/APP Self-assembled Bamboo Scrimber[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2023,38(3):203-210.[doi:10.3969/j.issn.1001-7461.2023.03.27]
点击复制

 竹束热处理对CS/APP自组装重组竹阻燃抑烟性能的影响()
分享到：

《西北林学院学报》[ISSN:1001-7461/CN:61-1202/S]

卷:
第38卷
期数:
2023年第3期
页码:
203-210
栏目:
出版日期:
2023-05-31

文章信息/Info

Title:
 Effect of Heat Treatment on the Flame Retardancy and Smoke Suppression Performance of CS/APP Self-assembled Bamboo Scrimber
文章编号:
1001-7461(2023)03-0203-08
作者:
 刘娇; 曹旭东; 尚诗媛; 蔡金澄; 母军*
 （木质材料科学与应用教育部重点实验室，北京林业大学 材料科学与技术学院，北京 100083）
Author(s):
 LIU Jiao; CAO Xu-dong; SHANG Shi-yuan; CAI Jin-cheng; MU Jun*
 (MOE Key Laboratory of Wood Material Science and Application,College of Materials Science and Technology,Beijing Forestry University,Beijing 100083,China)
关键词:
 ; 竹束; 重组竹; 热处理; 层层自组装; 阻燃处理
Keywords:
 ; bamboo bundle;  bamboo scrimber;  heat treatment;  layer by layer self-assembly;  flame retardant treatment
分类号:
S781.3
DOI:
10.3969/j.issn.1001-7461.2023.03.27
文献标志码:
A
摘要:
 壳聚糖（CS）/聚磷酸铵（APP）层层自组装（LBL）是一种表面改性工艺，通过对竹束单元进行热处理，研究其对CS-TiO2/APP自组装重组竹（BS）的阻燃抑烟性能的影响及协同关系。采用不同热处理温度（160、180 ℃）和处理时间（2、3、4 h）对竹束单元进行水蒸气保护的热处理，首先对不同的竹束特性进行研究，优选竹束热处理工艺条件，然后在竹束表面进行CS-TiO2/APP自组装后制备重组竹，分析热处理对重组竹阻燃抑烟性能的影响及与LBL阻燃层的协同作用。结果表明，热处理后的竹束热稳定性提高，同时表面阻燃涂层增重率相比未热处理提高了27.0%，LBL后的极限氧指数较未热处理直接负载的提高了14.4%。综合不同热处理工艺下竹束的特性以及和负载LBL涂层的竹束阻燃效果，确定160 ℃下3 h为重组竹的热处理工艺条件。通过锥形量热测试，热处理后的BS(W-HT)重组竹较BS重组竹，燃烧热释放速率峰值pk-HRR降低了30.1%，产烟速率pk-SPR峰值降低了50.8%，热处理后的BS(W-HT)/CS-TiO2/APP重组竹与BS/CS-TiO2/APP重组竹比较，pk-HRR降低了9.7%，pk-SPR降低了36.4%，CO产量峰值降低了24.15%。竹束热处理后的重组竹具有较好的阻燃抑烟效果，并且和CS-TiO2/APP层层自组装具有良好的协同作用，提高了竹束表面的CS-TiO2/APP自组装阻燃涂层的负载，减少了BS/CS-TiO2/APP重组竹板材的烟释放和有毒气体的生成。
Abstract:
 CS/APP layer by layer (LBL) self-assembly is a surface modification process.In this research,the effects of heat treatment on the flame retardancy and smoke suppression of CS-TiO2/APP self-assembled bamboo scrimber were studied.Different heat treatment temperatures (160,180 ℃) and treatment time (2,3,and 4 h) were used to conduct heat treatment for the bamboo bundles protected by steam.Firstly,the characteristics of different bamboo bundles were studied,and the suitable heat treatment conditions for the preparation of bamboo scrimber were determined.Then bamboo scrimbers were prepared after CS-TiO2/APP self-assembly on the bamboo bundle surface.The effects of heat treatment on the flame retardancy and smoke suppression of bamboo scrimber and synergistic effect with LBL flame retardant layer were analyzed.The weight gain rate of flame retardant coating on the surface of bamboo bundles after heat treatment was 27.0% higher than that of non-heat treatment,and limiting oxygen index of LBL was 14.4% higher than that of direct load without heat treatment.Based on characteristics of bamboo bundles under different heat treatment processes and flame retardant effect of bamboo bundles loaded with LBL coating,the heat treatment conditions of bamboo scrimber were determined as 160 ℃ for 3 h.The pk-HRR of BS(W-HT) was reduced by 30.1%,pk-SPR decreased by 50.8% compared with untreated BS,pk-HRR of BS(W-HT)/CS-TiO2/APP decreased by 9.7%,pk-HRR decreased by 36.4%,the peak CO yield decreased by 24.15% compared with BS/CS-TiO2/APP.Heat-treated bamboo scrimber has a good effect of flame retardancy and smoke suppression,and has a good synergistic effect with CS-TiO2/APP layer-by-layer self-assembly,which increases load of CS-TiO2/APP self-assembly flame retardant coating on surface,reduces smoke release and toxic gas formation of BS/CS-TiO2/APP bamboo scrimber.

相似文献/References:

[1]李亚藏,梁彦兰,王庆成. 铅对山梨和山荆子光合作用和叶绿素荧光特性的影响[J].西北林学院学报,2012,27(05):21.
　LI Ya-cang,LIANG Yan-lan,WANG Qing-cheng. Influence of Pb on Photosynthesis and Chlorophyll Fluorescence Characteristics in Pyrus ussuriensis and Malus baccata [J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2012,27(3):21.
[2]张小咏,李佳,杨艳昭,等. 基于SWAT模型的长江源区径流模拟[J].西北林学院学报,2012,27(05):38.
　ZHANG Xiao-yong,LI Jia,YANG Yan-zhao,et al. Runoff Simulation of the Catchment of the Headwaters of the Yangtze River Based on SWAT Model[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2012,27(3):38.
[3]杨红旗,陈广辉,王金林. PVAc改性酚醛树脂制备铝木复合材料研究[J].西北林学院学报,2013,28(01):170.[doi:10.3969/j.issn.1001-7461.2013.01.34]
　YANG Hong-qi,CHEN Guang-hui,WANG Jin-lin. PF Adhesive Modified by PVAc for Manufacturing Technology of Decorative Fiberboard with Aluminum Foils[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(3):170.[doi:10.3969/j.issn.1001-7461.2013.01.34]
[4]江涛,李秀荣,谢延军,等. 微波预处理对巨尾桉木材渗透性的影响[J].西北林学院学报,2013,28(01):174.[doi:10.3969/j.issn.1001-7461.2013.01.35]
　JIANG Tao,LI Xiu-rong,XIE Yan-jun,et al. Effects of Microwave Pretreatment on the Permeability of Eucalyptus grandis×Eucalyptus urophylla[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(3):174.[doi:10.3969/j.issn.1001-7461.2013.01.35]
[5]牛晓霆,王逢瑚,曹新民. 明清家具匠师原木下料的工艺原则及措施[J].西北林学院学报,2013,28(01):178.[doi:10.3969/j.issn.1001-7461.2013.01.36]
　NIU Xiao-ting,WANG Feng-hu,CAO Xin-min. Techniques and Principles of Log Cuttings of Furniture Makers in Ming and Qing Dynasties[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(3):178.[doi:10.3969/j.issn.1001-7461.2013.01.36]
[6]吕金阳,覃卓凯,舒辉,等. 银杉木材构造美学价值[J].西北林学院学报,2013,28(01):183.[doi:10.3969/j.issn.1001-7461.2013.01.37]
　LV Jin-yang,QIN Zhuo-kai,SHU Hui,et al. Esthetical Values in Wood Structure of Cathaya argyrophylla[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(3):183.[doi:10.3969/j.issn.1001-7461.2013.01.37]
[7]杨艳红,张海敏,孙景荣. 基于传统文化视角的现代家具设计探析[J].西北林学院学报,2013,28(01):188.[doi:10.3969/j.issn.1001-7461.2013.01.38]
　YANG Yan-hong,ZHANG Hai-min,SUN Jing-rong. Study of Modern Furniture Design Based on Traditional Culture[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(3):188.[doi:10.3969/j.issn.1001-7461.2013.01.38]
[8]黄圣游,叶喜. 新中式家具“中式”传统的界定[J].西北林学院学报,2013,28(01):192.[doi:10.3969/j.issn.1001-7461.2013.01.39]
　HUANG Sheng-You,YE Xi. Definition of Traditional Element in New Chinese Style Furniture[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(3):192.[doi:10.3969/j.issn.1001-7461.2013.01.39]
[9]韩维生,赵明磊,王宏斌. 基于阈限理论的设计尺度体系[J].西北林学院学报,2013,28(01):197.[doi:10.3969/j.issn.1001-7461.2013.01.40]
　HAN Wei-sheng,ZHAO Ming-lei,WANG Hong-bin. Design Scale System Based on Threshold Theory[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(3):197.[doi:10.3969/j.issn.1001-7461.2013.01.40]
[10]宋杰,侯建军,申黎明. 按摩椅按摩头包覆层对按摩舒适性的影响[J].西北林学院学报,2013,28(01):202.[doi:10.3969/j.issn.1001-7461.2013.01.41]
　SONG Jie,HOU Jian-jun,SHEN Li-ming. Influence of Massager Coat Layer of Massage Chairs on the Degree of Comfort[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(3):202.[doi:10.3969/j.issn.1001-7461.2013.01.41]

备注/Memo

备注/Memo:
 收稿日期：2022-06-18修回日期：2022-11-04
基金项目：北京林业大学青年教师科学研究中长期项目（2015ZCQ-CL-01）。
第一作者：刘娇。研究方向：木质材料制备及阻燃。E-mail：liujiao0829@qq.com
*通信作者：母军，博士，教授，博士生导师。研究方向：木质生物质材料利用。E-mail：mujun@bjfu.edu.cn
更新日期/Last Update: