[1]吴志刚,张本刚,梁坚坤,等. 大豆蛋白-三聚氰胺-尿素-甲醛树脂胶黏剂固化剂的研究[J].西北林学院学报,2019,34(5):212-217.[doi:10.3969/j.issn.1001-7461.2019.05.33]
　WU Zhi-gang,ZHANG Ben-gang,LIANG Jian-kun,et al. Development of Curing Agent of Soy Protein-Melamine-Urea-Formaldehyde (SMUF) Resin[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2019,34(5):212-217.[doi:10.3969/j.issn.1001-7461.2019.05.33]
点击复制

 大豆蛋白-三聚氰胺-尿素-甲醛树脂胶黏剂固化剂的研究()
分享到：

《西北林学院学报》[ISSN:1001-7461/CN:61-1202/S]

卷:
第34卷
期数:
2019年第5期
页码:
212-217
栏目:
出版日期:
2019-09-30

文章信息/Info

Title:
 Development of Curing Agent of Soy Protein-Melamine-Urea-Formaldehyde (SMUF) Resin
文章编号:
1001-7461(2019)05-0212-06
作者:
 吴志刚1; 2; 张本刚1; 梁坚坤3; 席雪冬1; 雷洪1; 余丽萍2; 周晓剑1*
 （1.西南林业大学，云南省木材胶黏剂及胶合制品重点实验室，云南 昆明 650224；2.贵州大学 林学院，贵州 贵阳 550025；3.凯里学院，贵州 黔东南 556011）
Author(s):
 WU Zhi-gang1; 2; ZHANG Ben-gang1; LIANG Jian-kun3; XI Xue-dong1; LEI Hong1; YU Li-ping2; ZHOU Xiao-jian1*
 (1.Yunnan Provincial Key Laboratory of Wood Adhesives and Glued Products,Southwest Forestry University,Kunming 650224,Yunnan China; 2.College of Forestry,Guizhou University,Guiyang 550025,Guizhou,China; 3.Kaili University,Qiandongnan 556011,Guizhou,China)
关键词:
 ; 大豆蛋白-三聚氰胺-尿素-甲醛树脂; 固化剂; 胶合性能; 固化特征; 热性能
Keywords:
 ; soy protein-melamine-urea-formaldehyde resin (SMUF) curing agent;  bonding performance;  curing behavior;  thermal performance
分类号:
S781.65
DOI:
10.3969/j.issn.1001-7461.2019.05.33
文献标志码:
A
摘要:
 以大豆蛋白降解液、三聚氰胺、尿素和高浓度甲醛为原料，合成了一种低摩尔比的大豆蛋白-三聚氰胺-尿素-甲醛共缩聚树脂胶黏剂（SMUF）。选用(NH4)2SO4、(NH4)2S2O8、(NH4)2HPO4和H3PO4作为SMUF树脂的固化剂，研究了固化剂对SMUF树脂基本理化性能的影响。结果表明：1）传统固化剂(NH4)2SO4不能使SMUF树脂充分固化，最终树脂胶合强度低、耐水性差，固化后的胶层断面疏松、多孔；2）H3PO4和(NH4)2S2O8属于中强酸体系，两者均能一定程度加速SMUF树脂的固化，树脂胶合强度和耐水性均得到改善，固化温度显著降低，固化放热量有所提高；3）(NH4)2HPO4是一种缓冲型酸，其催化SMUF树脂的固化速度较为均匀，树脂综合性能较优，树脂的胶合强度和耐水性较好，固化温度也有所降低，树脂交联程度高，树脂固化层断面相对较为均匀。
Abstract:
 A soy protein-melamine-urea-formaldehyde resin with lower molar ratio was prepared by using soy protein degradation fluid,melamine,urea and high concentration formaldehyde.(NH4)2SO4,(NH4)2S2O8,(NH4)2HPO4 and H3PO4 were as used to investigate the effect of these curing agents on the basci phycial-chemcial properties of SMUF resin.The results showed that 1) (NH4)2SO4 could not fully cure SMUF resin,the resultant resin had lower bonding strength,inferior water resistance,and loose and porous curing interface.2) H3PO4 and (NH4)2S2O8 belonged to medium strong acid system,they could accelerate the curing speed of SMUF resin in some extents.The bonding strength and water resistance were improved,although curing temperature decreased significantly,curing exothermic value increased.3) (NH4)2HPO4 was a buffering acid,the curing speed was very uniform.The resin performances,bonding strength,and water resistance were better.The curing temperature was lower and the resin curing interface was uniform.

相似文献/References:

[1]李亚藏,梁彦兰,王庆成. 铅对山梨和山荆子光合作用和叶绿素荧光特性的影响[J].西北林学院学报,2012,27(05):21.
　LI Ya-cang,LIANG Yan-lan,WANG Qing-cheng. Influence of Pb on Photosynthesis and Chlorophyll Fluorescence Characteristics in Pyrus ussuriensis and Malus baccata [J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2012,27(5):21.
[2]张小咏,李佳,杨艳昭,等. 基于SWAT模型的长江源区径流模拟[J].西北林学院学报,2012,27(05):38.
　ZHANG Xiao-yong,LI Jia,YANG Yan-zhao,et al. Runoff Simulation of the Catchment of the Headwaters of the Yangtze River Based on SWAT Model[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2012,27(5):38.
[3]杨红旗,陈广辉,王金林. PVAc改性酚醛树脂制备铝木复合材料研究[J].西北林学院学报,2013,28(01):170.[doi:10.3969/j.issn.1001-7461.2013.01.34]
　YANG Hong-qi,CHEN Guang-hui,WANG Jin-lin. PF Adhesive Modified by PVAc for Manufacturing Technology of Decorative Fiberboard with Aluminum Foils[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(5):170.[doi:10.3969/j.issn.1001-7461.2013.01.34]
[4]江涛,李秀荣,谢延军,等. 微波预处理对巨尾桉木材渗透性的影响[J].西北林学院学报,2013,28(01):174.[doi:10.3969/j.issn.1001-7461.2013.01.35]
　JIANG Tao,LI Xiu-rong,XIE Yan-jun,et al. Effects of Microwave Pretreatment on the Permeability of Eucalyptus grandis×Eucalyptus urophylla[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(5):174.[doi:10.3969/j.issn.1001-7461.2013.01.35]
[5]牛晓霆,王逢瑚,曹新民. 明清家具匠师原木下料的工艺原则及措施[J].西北林学院学报,2013,28(01):178.[doi:10.3969/j.issn.1001-7461.2013.01.36]
　NIU Xiao-ting,WANG Feng-hu,CAO Xin-min. Techniques and Principles of Log Cuttings of Furniture Makers in Ming and Qing Dynasties[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(5):178.[doi:10.3969/j.issn.1001-7461.2013.01.36]
[6]吕金阳,覃卓凯,舒辉,等. 银杉木材构造美学价值[J].西北林学院学报,2013,28(01):183.[doi:10.3969/j.issn.1001-7461.2013.01.37]
　LV Jin-yang,QIN Zhuo-kai,SHU Hui,et al. Esthetical Values in Wood Structure of Cathaya argyrophylla[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(5):183.[doi:10.3969/j.issn.1001-7461.2013.01.37]
[7]杨艳红,张海敏,孙景荣. 基于传统文化视角的现代家具设计探析[J].西北林学院学报,2013,28(01):188.[doi:10.3969/j.issn.1001-7461.2013.01.38]
　YANG Yan-hong,ZHANG Hai-min,SUN Jing-rong. Study of Modern Furniture Design Based on Traditional Culture[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(5):188.[doi:10.3969/j.issn.1001-7461.2013.01.38]
[8]黄圣游,叶喜. 新中式家具“中式”传统的界定[J].西北林学院学报,2013,28(01):192.[doi:10.3969/j.issn.1001-7461.2013.01.39]
　HUANG Sheng-You,YE Xi. Definition of Traditional Element in New Chinese Style Furniture[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(5):192.[doi:10.3969/j.issn.1001-7461.2013.01.39]
[9]韩维生,赵明磊,王宏斌. 基于阈限理论的设计尺度体系[J].西北林学院学报,2013,28(01):197.[doi:10.3969/j.issn.1001-7461.2013.01.40]
　HAN Wei-sheng,ZHAO Ming-lei,WANG Hong-bin. Design Scale System Based on Threshold Theory[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(5):197.[doi:10.3969/j.issn.1001-7461.2013.01.40]
[10]宋杰,侯建军,申黎明. 按摩椅按摩头包覆层对按摩舒适性的影响[J].西北林学院学报,2013,28(01):202.[doi:10.3969/j.issn.1001-7461.2013.01.41]
　SONG Jie,HOU Jian-jun,SHEN Li-ming. Influence of Massager Coat Layer of Massage Chairs on the Degree of Comfort[J].JOURNAL OF NORTHWEST FORESTRY UNIVERSITY,2013,28(5):202.[doi:10.3969/j.issn.1001-7461.2013.01.41]

备注/Memo

备注/Memo:
 收稿日期：2018-12-31修回日期：2019-01-17
基金项目：国家自然科学基金（31800481，31660176、31870546）；云南省教育厅科学研究基金项目（2017ZZX209）；贵州省科技支撑项目（黔科合支撑［2019］2308和［2019］2325）；贵州省林业厅项目（黔林科合［2017］14）；西南林业大学校启动基金项目（111814）。
作者简介：吴志刚，男，博士，副教授，研究方向：森林资源综合利用。E-mail：wzhigang9@163.com
*通信作者：周晓剑，男，博士，副研究员，研究方向：木材胶黏剂及复合材料。Email：xiaojianzhou@hotmail.com
更新日期/Last Update: